Activation of enamine by photoexcited organocatalyst assisted singlet oxygen: synthesis of oxazoles and quinoxalines

Author:

Elavarasan Selvaraj1,Preety Jeyaraj1,Kesavan M.2,Patel Ravi B.3ORCID,Baskar Baburaj1ORCID

Affiliation:

1. Laboratory of Sustainable Synthesis, Department of Chemistry, SRM Institute of Science and Technology, Kattankulatur, 603 203, Chengalpet (Dt), Tamilnadu, India

2. Interdisciplinary Institute of Indian System of Medicine (IIISM), SRM Institute of Science and Technology, Kattankulatur, 603 203, Chengalpet (Dt), Tamilnadu, India

3. Graduate School of Pharmacy, Gujarat Technological University, Ghandhinagar Campus, Ghandhinagar – 382028, Gujarat, India

Abstract

Herein, a novel transition-metal-free thiol-based donor–acceptor organophotocatalyst-assisted, singlet-oxygen-mediated tandem oxidative cyclization for the synthesis of substituted oxazoles in moderate-to-good yields is described.

Funder

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

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