Photochemical H<sub>2</sub> activation by an Zn–Fe heterometallic: a mechanistic investigation-Reference-Cited by-同舟云学术

Photochemical H₂ activation by an Zn–Fe heterometallic: a mechanistic investigation

Published:2024 Issue:4 Volume:15 Page:1424-1430
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Perez-Jimenez Marina¹^ORCID,Crimmin Mark R.¹^ORCID

Affiliation:

1. Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, 82 Wood Lane, White City, London, W12 0Z, UK

Abstract

Addition of H2 to a Zn–Fe complex was observed to occur under photochemical conditions (390 or 428 nm LED) and leads to the formation of a heterometallic dihydride complex.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05966A

Reference34 articles.

1. Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

2. Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate

3. Unexpected Electronic Process of H2 Activation by a New Nickel Borane Complex: Comparison with the Usual Homolytic and Heterolytic Activations

4. A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2

5. Activation of H2 over the Ru−Zn Bond in the Transition Metal−Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt]+

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