Nucleophilic aromatic substitution approach to phosphanyl-substituted diboraanthracenes: biphilic compounds with tunable electron affinities

Author:

Jin Tao1ORCID,Bolte Michael1ORCID,Lerner Hans-Wolfram1ORCID,Wagner Matthias1ORCID

Affiliation:

1. Institut für Anorganische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt (Main), Germany

Abstract

9,10-Dihydro-9,10-diboraanthracenes with one, two, or four Ph2P-substituents were prepared via nucleophilic aromatic substitution. P-oxidation, -sulfurization, or -methylation greatly facilitate the reduction of the compounds.

Funder

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference44 articles.

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