Clarifying the controversial catalytic active sites of Co3O4 for the oxygen evolution reaction

Author:

Xu Yong12345,Zhang Fengchu678910,Sheng Tian1112135ORCID,Ye Tao678910,Yi Ding678910,Yang Yijun678910ORCID,Liu Shoujie14155,Wang Xi678910ORCID,Yao Jiannian12345

Affiliation:

1. School of Chemical Engineering and Technology

2. Tianjin University; Institute of Molecular Plus

3. Tianjin University

4. Tianjin

5. P. R. China

6. Key Laboratory of Luminescence and Optical Information

7. Ministry of Education

8. Department of Physics

9. School of Science

10. Beijing Jiaotong University

11. College of Chemistry and Materials Science

12. Anhui Normal University

13. Wuhu

14. Chemistry and Chemical Engineering Guangdong Laboratory

15. Shantou 515031

Abstract

Controversial results still exist about the activities of tetrahedral (Co2+) and octahedral (Co3+) sites in Co3O4 toward the OER. Theoretical and experimental data confirm that octahedral sites are responsible for the OER, using model catalysts.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Beijing Jiaotong University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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