Rotaxanes composed of dibenzo-24-crown-8 and macrocyclic transition metal complexing tetraimine units
Author:
Affiliation:
1. Institute of Organic Chemistry
2. Polish Academy of Sciences
3. 01-224 Warszawa
4. Poland
5. Biological and Chemical Research Centre
6. Chemistry Department
7. University of Warsaw
8. 02-089 Warszawa
9. Faculty of Chemistry
10. 02-093 Warszawa
Abstract
New rotaxanes, composed of dibenzo-24-crown-8 and the axle containing two tetraazamacrocyclic Ni and/or Cu units, adopt either folded or extended conformations and di-Ni-rotaxanes exhibit a shuttling effect of DB24C8.
Funder
Narodowe Centrum Nauki
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ00909G
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