Alkyl-dependent self-assembly of the first red-emitting zwitterionic {Cu4I6} clusters from [alkyl-P(2-Py)3]+ salts and CuI: when size matters

Author:

Artem'ev Alexander V.12345ORCID,Pritchina Elena A.53467,Rakhmanova Marianna I.12345,Gritsan Nina P.53467ORCID,Bagryanskaya Irina Yu.53482,Malysheva Svetlana F.910114ORCID,Belogorlova Nataliya A.910114ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry

2. Siberian Branch of Russian Academy of Sciences

3. Novosibirsk 630090

4. Russian Federation

5. Novosibirsk State University (National Research University)

6. Voevodsky Institute of Chemical Kinetics and Combustion

7. 630090 Novosibirsk

8. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry

9. A. E. Favorsky Irkutsk Institute of Chemistry

10. Siberian Branch of the Russian Academy of Sciences

11. 664033 Irkutsk

Abstract

First examples of zwitterionic CuI-based complexes showing red photoluminescence are reported.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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