Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C–H borylation of heteroarenes-Reference-Cited by-同舟云学术

Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C–H borylation of heteroarenes

Published:2021 Issue:3 Volume:12 Page:1031-1037
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lipshultz Jeffrey M.¹²³⁴^ORCID,Fu Yue¹⁵⁶⁴,Liu Peng¹⁵⁶⁴^ORCID,Radosevich Alexander T.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

5. University of Pittsburgh

6. Pittsburgh

Abstract

A nontrigonal phosphorus triamide (1, P{N[o-NMe-C₆H₄]₂}) is shown to catalyze C–H borylation of electron-rich heteroarenes with pinacolborane (HBpin) in the presence of a mild chloroalkane reagent.

Funder

Camille and Henry Dreyfus Foundation

Division of Chemistry

Massachusetts Institute of Technology

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05620K

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