Dimerization of terminal alkynes promoted by a heterobimetallic Zr/Co complex-Reference-Cited by-同舟云学术

Dimerization of terminal alkynes promoted by a heterobimetallic Zr/Co complex

Published:2020 Issue:8 Volume:49 Page:2407-2411
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Beattie Jeffrey W.¹²³⁴^ORCID,Wang Canning¹²³⁴,Zhang Hongtu¹²³⁴,Krogman Jeremy P.⁵⁶⁷⁴⁸,Foxman Bruce M.⁵⁶⁷⁴^ORCID,Thomas Christine M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. The Ohio State University

3. Columbus

4. USA

5. Department of Chemistry

6. Brandeis University

7. Waltham

8. School of Physical Science and Technology

Abstract

A reduced Zr^IV/Co^−I heterobimetallic complex facilitates the formation of 1,3-enynes from terminal alkynes through a cooperative bimetallic C–H activation process.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00334D

Reference45 articles.

1. Recent Advances in the Transition-Metal-Catalyzed Regioselective Approaches to Polysubstituted Benzene Derivatives

2. The Dehydro-Diels−Alder Reaction

3. Conjugated Enynes as a New Type of Substrates for Olefin Metathesis

4. Tandem catalysis for asymmetric coupling of ethylene and enynes to functionalized cyclobutanes

5. Transition metal-catalyzed couplings of alkynes to 1,3-enynes: modern methods and synthetic applications

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