Arene C–H bond activation and methane formation by a methylplatinum(ii) complex: experimental and theoretical elucidation of the mechanism-Reference-Cited by-同舟云学术

Arene C–H bond activation and methane formation by a methylplatinum(ii) complex: experimental and theoretical elucidation of the mechanism

Published:2019 Issue:21 Volume:43 Page:8005-8014
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Nahaei Asma¹²³⁴⁵,Nabavizadeh S. Masoud¹²³⁴⁵^ORCID,Hosseini Fatemeh Niroomand²⁶⁷⁸⁹^ORCID,Hoseini S. Jafar¹²³⁴⁵^ORCID,Abu-Omar Mahdi M.¹⁰¹¹¹²¹³¹⁴^ORCID

Affiliation:

1. Professor Rashidi Laboratory of Organometallic Chemistry

2. Department of Chemistry

3. College of Sciences

4. Shiraz University

5. Shiraz

6. Shiraz Branch

7. Islamic Azad University

8. Shiraz 71993-37635

9. Iran

10. Department of Chemistry and Biochemistry

11. University of California

12. Santa Barbara

13. California 93106

14. USA

Abstract

A combined experimental/computational investigation reveals that the cyclometalation of [PtMe₂(DMSO)₂], 1, by HC^N ligands proceeds via HC^N coordination through the N donor atom, oxidative addition of the arene C–H bond, and final dissociation of methane from a platinum hydride complex.

Funder

Shiraz University

Iran National Science Foundation

University of California, Santa Barbara

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ01968E

Reference51 articles.

1. Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends