Rationalization of the selectivity between 1,3- and 1,2-migration: a DFT study on gold(i)-catalyzed propargylic ester rearrangement-Reference-Cited by-同舟云学术

Rationalization of the selectivity between 1,3- and 1,2-migration: a DFT study on gold(i)-catalyzed propargylic ester rearrangement

Published:2016 Issue:14 Volume:14 Page:3558-3563
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Jiang Jingxing¹²³⁴⁵,Liu Yan⁶⁷⁸⁹¹⁰,Hou Cheng¹²³⁴⁵,Li Yinwu¹²³⁴⁵,Luan Zihong¹²³⁴⁵,Zhao Cunyuan¹²³⁴⁵,Ke Zhuofeng¹²³⁴⁵

Affiliation:

1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry

2. School of Chemistry and Chemical Engineering

3. School of Materials Science and Engineering

4. Sun Yat-sen University

5. Guangzhou 510275

6. School of Chemical Engineering and Light Industry

7. Guangdong University of Technology

8. Higher Education Mega Center

9. Guangzhou 510006

10. P. R. China

Abstract

A general theoretical mode, based on the resonance structure of gold activated propargylic ester complexes, is presented to rationalize the regioselectivity of the gold catalyzed rearrangement of propargylic esters.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00215C

Reference51 articles.

1. Gold-catalyzed decorations of arenes and heteroarenes with C–C multiple bonds

2. Gold catalyzed oxycyclizations of alkynols and alkyndiols

3. Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions

4. The Catalysis Gold Rush: New Claims

5. Homogeneous Gold Catalysis Beyond Assumptions and Proposals-Characterized Intermediates

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