Spatio-temporal detachment of homogeneous electron transfer in controlling selectivity in mediated organic electrosynthesis

Author:

Hodgson Jack W.1ORCID,Folgueiras-Amador Ana A.1ORCID,Pletcher Derek1,Harrowven David C.1ORCID,Denuault Guy1ORCID,Brown Richard C. D.1ORCID

Affiliation:

1. School of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, UK

Abstract

Simulations support time dependent detachment of homogeneous ET and coupled chemistry under mediated electroreduction when Eele < EM < EArI.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

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5. J.Lalevée and J. P.Fouassier , in Encyclopedia of Radicals in Chemistry, Biology and Materials, Vol 2: Synthetic Strategies and Applications , ed. C. Chatgilialoglu and A. Studer , John Wiley and Sons , Weinheim , 2012

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