Lithiated sulfoxides: α-sulfinyl functionalized carbanions

Author:

Ludwig Gerd1234,Rüffer Tobias1564,Hoppe André1234,Walther Till1234,Lang Heinrich1564,Ebbinghaus Stefan G.1234,Steinborn Dirk1234

Affiliation:

1. Institute of Chemistry

2. Martin Luther University Halle-Wittenberg

3. D-06120 Halle

4. Germany

5. Chemnitz University of Technology

6. D-09107 Chemnitz

Abstract

Lithiated sulfoxides of the type [Li2{CRR′S(O)Ar}2(TMEDA)2], their molecular structures, and diastereoselective C–C bond formation reactions with benzaldehyde and benzophenone are presented.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference54 articles.

1. T. Toru and C.Bolm, Organosulfur Chemistry in Asymmetric Synthesis, Wiley, Hoboken, 1st edn, 2008

2. R. J. W. Cremlyn , An Introduction to Organosulfur Chemistry, Wiley, Chichester, 1st edn, 1996

3. E. Block , Organic Chemistry: Reactions of Organosulfur Compounds, ed. A. T. Blomquist and H. H. Wasserman, Academic Press, New York, 1978, p. 37

4. K. Ogura , Comprehensive Organic Synthesis, Selectivity, Strategy, Efficiency in Modern Organic Chemistry, 1991, 1, 505

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