Generation and trapping of electron-deficient 1,2-cyclohexadienes. Unexpected hetero-Diels–Alder reactivity

Author:

Wang Baolei12345,Constantin Marius-Georgian12345,Singh Simarpreet1678,Zhou Yuqiao12345,Davis Rebecca L.1678ORCID,West F. G.12345ORCID

Affiliation:

1. Department of Chemistry

2. University of Alberta

3. E3-43 Gunning-Lemieux Chemistry Centre

4. Edmonton

5. Canada T6G 2G2

6. University of Manitoba

7. Winnipeg

8. Canada R3T 2N2

Abstract

Keto-substituted 1,2-cyclohexadienes undergo a novel dimerization process and can be trapped with various furan-based 1,3-dienes or enamine dienophiles.

Funder

American Chemical Society Petroleum Research Fund

Natural Sciences and Engineering Research Council of Canada

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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