Optically active P5-deltacyclenes: selective oxidation, ligand properties, and a diastereoselective rearrangement reaction
Author:
Affiliation:
1. Department Chemie & Pharmazie
2. Universität Erlangen-Nürnberg
3. 91058 Erlangen
4. Germany
5. 91054 Erlangen
Abstract
Tuning the ligand properties of chiral P–C cage compounds: selective mono oxidation of P5-deltacyclene opens the gate to a phosphinious acid ligand.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00548A
Reference78 articles.
1. Acyl-und Alkylidenphosphane, XV 2.2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1/ Acyl- and Alkylidenephosphines, XV 2,2-Dimethylpropvlidynephosphine, a Stable Compound with a Phosphorus Atom of Coordination Number 1
2. Polycyclische Polyphospha-kohlenwasserstoffe
3. Tetra-tert-butyltetraphosphacubane: The First Thermal Cyclooligomerization of a Phosphaalkyne
4. Unusual oxidative coupling of 1,2,4-triphosphacyclopentadienyl and 1,3-diphosphacyclopentadienyl anions. Synthesis and molecular structure of the novel pentaphosphorus cage compound P5C5But5
5. Homo-Diels-Alder and ene reactions of phosphaalkynes
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1. Three-Membered Rings With Two Heteroatoms Including Phosphorus to Bismuth;Comprehensive Heterocyclic Chemistry IV;2022
2. Stereoselective P5-Deltacyclene Alkylation, an Efficient Route to New Asymmetric P-C-Cage Compounds;Zeitschrift für anorganische und allgemeine Chemie;2017-06-07
3. Dimeric P 5 -deltacyclene complexes: Variation of bridging modes and intact or partially opened P C cage ligand structures;Journal of Organometallic Chemistry;2016-10
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