Regioselective access of alkylidendibenzo[c,f]oxocine framework via cyclocarbopalladation/cross-coupling cascade reactions and reductive Heck strategy-Reference-Cited by-同舟云学术

Regioselective access of alkylidendibenzo[c,f]oxocine framework via cyclocarbopalladation/cross-coupling cascade reactions and reductive Heck strategy

Published:2017 Issue:8 Volume:41 Page:2927-2933
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ghosh Tapas¹²³⁴^ORCID

Affiliation:

1. Institute of Organic Chemistry

2. University of Würzburg

3. 97074 Würzburg

4. Germany

Abstract

Palladium-catalyzed dual strategies of cascade cyclocarbopalladation/cross-coupling of alkynes and a reductive Heck reaction have been developed to construct dibenzo[c,f]oxocine frameworks with tri- and tetra-substituted exo-cyclic alkenes with high stereo- and regio-control.

Funder

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ03825E

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1. The Structure and Probable Biogenesis of Helianane, a Heterocyclic Sesquiterpene, from the Indo-Pacific Sponge Haliclona ?fascigera

2. Acremine G, Dimeric Metabolite from Cultures of Acremonium byssoides A20

3. Novel sesquiterpene from bioactive fractions of cultivar sunflowers