Formation of exceptional monomeric YPhos–PdCl<sub>2</sub> complexes with high activities in coupling reactions-Reference-Cited by-同舟云学术

Formation of exceptional monomeric YPhos–PdCl₂ complexes with high activities in coupling reactions

Published:2022 Issue:45 Volume:13 Page:13552-13562
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rodstein Ilja¹,Kelling Leif¹,Löffler Julian¹,Scherpf Thorsten¹,Sarbajna Abir¹^ORCID,Andrada Diego M.²^ORCID,Gessner Viktoria H.¹^ORCID

Affiliation:

1. Faculty of Chemistry and Biochemistry, Chair of Inorganic Chemistry II, Ruhr University Bochum, Universitätsstr. 150, 44801 Bochum, Germany

2. General and Inorganic Chemistry Department, University of Saarland, Campus C4.1, 66123 Saarbruecken, Germany

Abstract

Ylide-substituted phosphines form monomer, air-stable PdCl2 complexes which feature a unique bonding situation between the metal and the phosphine and ylide donor and exhibit high efficiencies as precatalysts in C–C and C–X cross-coupling reactions.

Funder

Verband der Chemischen Industrie

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04523K

Reference67 articles.

1. Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize