Rational design of efficient photosensitizers based on cyclometalated iridium(<scp>iii</scp>) complexes with 2-arylbenzimidazole and aromatic 1,3-diketone ligands-Reference-Cited by-同舟云学术

Rational design of efficient photosensitizers based on cyclometalated iridium(iii) complexes with 2-arylbenzimidazole and aromatic 1,3-diketone ligands

Published:2023 Issue:44 Volume:52 Page:16261-16275
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tatarin Sergei V.¹^ORCID,Meshcheriakova Elizaveta A.¹²,Kozyukhin Sergey A.¹,Emets Victor V.³,Bezzubov Stanislav I.¹^ORCID

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russia

2. Lomonosov Moscow State University, Lenin's Hills, 1-3, Moscow, 119991, Russia

3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119071, Russia

Abstract

Design and synthesis of cyclometalated iridium(iii) complexes with 2-arylbenzimidazoles and 1,3-diketones demonstrating strong light absorption up to 500 nm, the desired excited state localization and good photovoltaic performance are reported.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02789A

Reference70 articles.

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2. Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes

3. Asymmetric photoredox transition-metal catalysis activated by visible light

4. High Triplet Energy Iridium(III) Isocyanoborato Complex for Photochemical Upconversion, Photoredox and Energy Transfer Catalysis

5. A Robust Visible-Light-Harvesting Cyclometalated Ir(III) Diimine Sensitizer for Homogeneous Photocatalytic Hydrogen Production

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