π-Extended ligands with dual-binding behavior: hindered rotation unlocks unexpected reactivity in cyclometalated Pt complexes-Reference-Cited by-同舟云学术

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π-Extended ligands with dual-binding behavior: hindered rotation unlocks unexpected reactivity in cyclometalated Pt complexes

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ota Seiya¹^ORCID,Soto Miguel A.¹^ORCID,Patrick Brian O.¹^ORCID,Kamal Saeid¹^ORCID,Lelj Francesco²^ORCID,MacLachlan Mark J.¹³⁴^ORCID

Affiliation:

1. Department of Chemistry University of British Columbia, 2036 Main Mall, Vancouver, V6T 1Z1, Canada

2. La.M.I.and LaSCAMM INSTM Sezione Basilicata, Dipartiento di Scienze, Università della Basilicata, via dell'Ateneo Lucano 10, Potenza, 85100, Italy

3. Stewart Blusson Quantum Matter Institute University of British Columbia, 2355 East Mall, Vancouver, BC, V6T 1Z4, Canada

4. WPI Nano Life Science Institute Kanazawa University, Kanazawa, 920-1192, Japan

Abstract

Naphthalenyl- and anthracenylpyridine cyclometalating ligands bind to Pt in different ways, which can be used to tune their emissive properties.

Funder

Canada Research Chairs

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC04799K

Reference54 articles.

1. Tuning the reactivity of metals held in a rigid ligand environment

2. Synthesis, Characterization, and Spectroscopy of Dipyridocatecholate Complexes of Platinum

3. Luminescent Pincer Platinum(II) Complexes with Emission Quantum Yields up to Almost Unity: Photophysics, Photoreductive CC Bond Formation, and Materials Applications

4. Chromic Platinum Complexes Containing Multidentate Ligands

5. Cyclometalation of 2,2′-Bipyridine. Mono- and Dinuclear C,N Platinum(II) Derivatives

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