Rh(<scp>i</scp>)-catalyzed site-selective hydroacylation of alkenyl-bearing allylic alcohols with non-chelating aldehydes controlled by <i>in situ</i> generated carbonyl group-Reference-Cited by-同舟云学术

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Rh(i)-catalyzed site-selective hydroacylation of alkenyl-bearing allylic alcohols with non-chelating aldehydes controlled by in situ generated carbonyl group

Published:2022 Issue:41 Volume:46 Page:19802-19807
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Fu-Gang¹,Gong Fei-Yuan¹,Cao Juan¹,Wang Ji-Cong²,Tian Kai-Qiang¹,Zhao Jinbo¹,Li Hong-Shuang¹^ORCID

Affiliation:

1. School of Pharmaceutical Sciences, Shandong First Medical University & Shandong Academy of Medical Sciences, Taian 271016, P. R. China

2. People's Hospital of Juxian, Rizhao 276599, P. R. China

Abstract

A rhodium(i)-catalyzed hydroacylation process allows the regioselective synthesis of 1,5-diketones from alkenyl-bearing allylic alcohols involving a stable six-membered rhodacycle intermediate.

Funder

Youth Innovation Team Project for Talent Introduction and Cultivation in Universities of Shandong Province

Natural Science Foundation of Shandong Province

Shandong First Medical University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ04607E

Reference55 articles.

1. Teaching Aldehydes New Tricks Using Rhodium- and Cobalt-Hydride Catalysis

2. Recent advances in transition metal-catalysed hydroacylation of alkenes and alkynes

3. Catalytic Transformation of Aldehydes with Nickel Complexes through η2 Coordination and Oxidative Cyclization

4. Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

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