Rhodium(<scp>iii</scp>)-catalyzed oxidative cross-coupling of benzoxazinones with styrenes <i>via</i> C

Rhodium(iii)-catalyzed oxidative cross-coupling of benzoxazinones with styrenes via C–H activation

Published:2023 Issue:4 Volume:21 Page:797-806
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yang Xifa¹^ORCID,Li Song¹,He Yuhao¹,Dai Danhua¹,Bao Mengyao¹,Luo Ziyang¹,Liu Xiangyang¹,Geng Yuehua¹,Fan Liangxin²^ORCID

Affiliation:

1. Institute of Pesticide, College of Plant Protection, Henan Agricultural University, Zhengzhou, 450002, China

2. College of Sciences, Henan Agricultural University, Zhengzhou, 450002, China

Abstract

Reported herein is a Rh(iii)-catalyzed C–H cross-coupling of benzoxazinones and unactivated styrenes to furnish vinylarene scaffolds. Mechanistic studies, gram-scale experiment and further transformations of this method were also demonstrated.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Henan Province

Science and Technology Department of Henan Province

Key Scientific Research Project of Colleges and Universities in Henan Province

Henan Agricultural University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB01655A

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