A tetragonal polymorph of SrMn2P2made under high pressure – theory and experiment in harmony
Author:
Affiliation:
1. Department of Chemistry
2. Louisiana State University
3. Baton Rouge
4. USA
5. Faculty of Applied Physics and Mathematics
6. Gdansk University of Technology
7. 80-233 Gdansk
8. Poland
9. Princeton University
10. Princeton
Abstract
A trigonal–tetragonal phase transition in SrMn2P2is proposed and confirmed experimentally under high pressure. At ambient pressure, SrMn2P2crystallizes in the primitive trigonal La2O3structure type (space groupP3̄m1) in blue. Under high pressure, the tetragonal ThCr2Si2structure type (space groupI4/mmm) in red is more stable.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00781G
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