Discovery of main group single Sb–N4 active sites for CO2 electroreduction to formate with high efficiency

Author:

Jiang Zhuoli12345,Wang Tao678910ORCID,Pei Jiajing1112135,Shang Huishan12345,Zhou Danni12345,Li Haijing141516175,Dong Juncai141516175,Wang Yu181920215,Cao Rui22232410,Zhuang Zhongbin1112135ORCID,Chen Wenxing12345ORCID,Wang Dingsheng2526275ORCID,Zhang Jiatao12345ORCID,Li Yadong2526275ORCID

Affiliation:

1. Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

2. School of Materials Science and Engineering

3. Beijing Institute of Technology

4. Beijing 100081

5. China

6. SUNCAT Center for Interface Science and Catalysis

7. Department of Chemical Engineering

8. Stanford University

9. Stanford

10. USA

11. College of Chemical Engineering

12. Beijing University of Chemical Technology

13. Beijing 100029

14. Beijing Synchrotron Radiation Facility

15. Institute of High Energy Physics

16. Chinese Academy of Sciences

17. Beijing

18. Shanghai Synchrotron Radiation Facility

19. Shanghai Institute of Applied Physics

20. Chinese Academy of Science

21. Shanghai 201800

22. Stanford Synchrotron Radiation Lightsource

23. SLAC National Accelerator Laboratory

24. Menlo Park

25. Department of Chemistry

26. Tsinghua University

27. Beijing 100084

Abstract

We discover that an Sb single atom material consisting of Sb–N4 moieties anchored on N-doped carbon nanosheets can serve as a CO2RR catalyst to produce formate with high efficiency.

Funder

National Natural Science Foundation of China

Beijing Institute of Technology Research Fund Program for Young Scholars

Fundamental Research Funds for the Central Universities

National Basic Research Program of China

Science and Technology Planning Project of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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