Unraveling high alkene selectivity at full conversion in alkyne hydrogenation over Ni under continuous flow conditions-Reference-Cited by-同舟云学术

Unraveling high alkene selectivity at full conversion in alkyne hydrogenation over Ni under continuous flow conditions

Published:2022 Issue:17 Volume:12 Page:5265-5273
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Bakuru Vasudeva Rao¹,Fazl-Ur-Rahman Kashifa²,Periyasamy Ganga²^ORCID,Velaga Bharath³^ORCID,Peela Nageswara Rao³^ORCID,DMello Marilyn Esclance¹^ORCID,Kanakikodi Kempanna S.¹^ORCID,Maradur Sanjeev P.¹^ORCID,Maji Tapas Kumar⁴^ORCID,Kalidindi Suresh Babu⁵^ORCID

Affiliation:

1. Materials Science and Catalysis Division, Poornaprajna Institute of Scientific Research, Devanahalli, Bangalore Rural-562164, India

2. Department of Chemistry, Bangalore University, Bangalore-56, India

3. Department of Chemical Engineering, Indian Institution of Technology, Guwahati, Guwahati, Assam, India-781039

4. Molecular Materials Laboratory, CPMU, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India

5. Department of Inorganic and Analytical Chemistry, School of Chemistry, Andhra University, Visakhapatnam, India-530003

Abstract

Carbon dissolution in Ni lattices decreased the interaction of alkenes with the catalyst surface and gave an elusive combination of full phenyl acetylene conversion and high styrene selectivity (92 ± 1%) under continuous flow conditions.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00875K

Reference79 articles.

1. Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction

2. Heterogeneous Catalytic Hydrogenation Reactions in Continuous-Flow Reactors

3. Understanding Palladium Hydrogenation Catalysts: When the Nature of the Reactive Molecule Controls the Nature of the Catalyst Active Phase