The mechanism of ionic Diels–Alder reactions. A DFT study of the oxa-Povarov reaction
Author:
Affiliation:
1. Universidad de Valencia
2. Departamento de Química Orgánica
3. Valencia, Spain
4. Universidad Andrés Bello
5. Facultad de Ciencias Exactas
6. Departamento de Ciencias Químicas
7. Laboratorio de Química Teórica
8. 8370146 Santiago, Chile
Abstract
Topological ELF analysis along these I-DA reactions indicates that both mechanisms present a similar C–C bond formation.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/RA/C3RA47805J
Reference60 articles.
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2. W. Carruthers , Cycloaddition Reactions in Organic Synthesis , Pergamon , Oxford , 1990
3. Understanding the mechanism of polar Diels–Alder reactions
4. I. Fleming , Molecular Orbitals and Organic Chemical Reactions , Wiley , 2009
5. Control of regiospecificity in ionic Diels-Alder reactions. The use of allylic alcohols and allylic ethers as precursors of dienophilic allyl cations
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