The effect of particle size, morphology and support on the formation of palladium hydride in commercial catalysts

Author:

Parker Stewart F.1234ORCID,Walker Helen C.1234,Callear Samantha K.1234,Grünewald Elena567,Petzold Tina567,Wolf Dorit567,Möbus Konrad567,Adam Julian567,Wieland Stefan D.567,Jiménez-Ruiz Mónica8910,Albers Peter W.1167

Affiliation:

1. ISIS Facility

2. STFC Rutherford Appleton Laboratory

3. Didcot

4. UK

5. Evonik Resource Efficiency GmbH

6. D-63457 Hanau-Wolfgang

7. Germany

8. Institut Laue-Langevin

9. CS 20156 38042 Grenoble Cedex 9

10. France

11. Evonik Technology and Infrastructure GmbH

Abstract

The influence of the support on the quantity of hydrogen present in a supported palladium catalyst is characterised. The on-top hydrogen on β-PdH is observed for the first time.

Funder

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference53 articles.

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3. C. W. Jones , Applications of Hydrogen Peroxide and Derivatives , RSC Clean Technology Monographs (Royal Society of Chemistry) , Cambridge , 1999

4. Development of an anthraquinone process for the production of hydrogen peroxide in a trickle bed reactor—From bench scale to industrial scale

5. G. Goor , J.Glenneberg and S.Jacobi , in Ullmanns's Encyclopedia of Industrial Chemistry , Wiley-VCH , Weinheim , 7th edn, 2012 , vol. 18 , pp. 393–427

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