High spin iron(<scp>ii</scp>) complexes based on imidazolyl- and 1,2,3-triazolyl-thione ligands and NCE (E = S, Se or BH<sub>3</sub>) co-ligands: effect of the S-functional group on the structural and magnetic properties-Reference-Cited by-同舟云学术

High spin iron(ii) complexes based on imidazolyl- and 1,2,3-triazolyl-thione ligands and NCE (E = S, Se or BH₃) co-ligands: effect of the S-functional group on the structural and magnetic properties

Published:2022 Issue:31 Volume:46 Page:14910-14921
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Plaza-Lozano Diego¹^ORCID,Ramírez-Palma David¹,Vela Alberto¹^ORCID,Olguín Juan¹^ORCID

Affiliation:

1. Departamento de Química, Centro de Investigación y de Estudios Avanzados del IPN (CINVESTAV), Avenida IPN 2508, Col. San Pedro Zacatenco, Ciudad de México 07360, Mexico

Abstract

Differing magnetic behaviour in complexes of the type [FeII(N2S2)(NCE)2]: thione-based complexes are stabilised in the HS-state, whilst a previously reported picolylbenzylthioether–iron(ii) complex shows a hysteretic spin crossover behaviour.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ01989B

Reference58 articles.

1. Iron(III) and iron(II) complexes of 1-thia-4,7-diazacyclononane ([9]aneN2S) and 1,4-dithia-7-azacyclononane ([9]aneNS2). X-Ray structural analyses, magnetic susceptibility, Mössbauer, EPR and electronic spectroscopy †

2. Synthesis, Molecular Structure, and Physical Properties of the Complexes [{PhB(pz) 2 (CH 2 SMe)} 2 M] (M = Mn II , Fe II ; pz = pyrazol‐1‐yl) Containing a Novel [ N , N , S ]‐Heteroscorpionate Ligand

3. Four-Site Cooperative Spin Crossover in a Mononuclear FeIIComplex

4. Reversible Guest Binding in a Non‐Porous Fe II Coordination Polymer Host Toggles Spin Crossover

5. First Iron(II) Spin-crossover Complex with an N5S Coordination Sphere

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