Connecting the complex microstructure of LDPE to its rheology and processing properties via a combined fractionation and modelling approach

Author:

Zentel Kristina Maria12ORCID,Eselem Bungu Paul Severin3ORCID,Degenkolb Jonas2,Pasch Harald3ORCID,Busch Markus2ORCID

Affiliation:

1. Universität Hamburg, Institute for Technical and Macromolecular Chemistry, Bundesstr. 45, 20146 Hamburg, Germany

2. Technical University of Darmstadt, Institute for Technical and Macromolecular Chemistry, Alarich-Weiß-Straße 8, 64287 Darmstadt, Germany

3. University of Stellenbosch, Department of Chemistry and Polymer Science, PO Box X1, 7602 Matieland, South Africa

Abstract

The complex microstructure of LDPE regarding branching and molecular weight was correlated to its rheology and processing properties via preparative fractionation and modelling.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference64 articles.

1. Plastics , Plastics – the Facts 2016-An analysis of European and plastics and production and demand and waste data , 2016

2. Chain Length Distributions of Polyolefins Made with Coordination Catalysts at Very Short Polymerization Times – Analytical Solution and Monte Carlo Simulation

3. K. S.Whiteley , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2000

4. Colloquium: Laws controlling crystallization and melting in bulk polymers

5. Comprehensive analysis of branched polyethylene: the multiple preparative fractionation concept

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