Chaotropic anion based “water-in-salt” electrolyte realizes a high voltage Zn–graphite dual-ion battery

Author:

Zafar Zahid Ali12ORCID,Abbas Ghulam23,Knizek Karel4,Silhavik Martin1ORCID,Kumar Prabhat1,Jiricek Petr5,Houdková Jana5,Frank Otakar3ORCID,Cervenka Jiri1ORCID

Affiliation:

1. Department of Thin Films and Nanostructures, FZU – Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, 162 00 Prague 6, Czech Republic

2. Department of Physical Chemistry and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030, 128 43 Prague 2, Czech Republic

3. J. Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences, Dolejskova 2155/3, 183 23 Prague 8, Czech Republic

4. Department of Magnetics and Superconductors, FZU – Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, 162 00 Prague 6, Czech Republic

5. Department of Optical Materials, FZU – Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, 162 00 Prague 6, Czech Republic

Abstract

We report a high voltage Zn–graphite dual-ion battery based on Zn(ClO4)2 water-in-salt (WiS) electrolyte with a wide electrochemical window of 2.80 V and high oxidative stability of 2.60 V vs. Zn/Zn2+.

Funder

Ministerstvo Školství, Mládeže a Tělovýchovy

Grantová Agentura České Republiky

Grantová Agentura, Univerzita Karlova

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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