Assembly of a trapped valent Ce<sup>III/IV</sup>–TCNQ complex through metal–ligand redox cooperativity-Reference-Cited by-同舟云学术

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Assembly of a trapped valent Ce^III/IV–TCNQ complex through metal–ligand redox cooperativity

Published:2024 Issue:54 Volume:60 Page:6909-6912
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Gupta Himanshu¹^ORCID,Vincenzini Brett D.¹,Bacon Alexandra M.¹,Schelter Eric J.¹^ORCID

Affiliation:

1. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA

Abstract

A trapped-valent CeIII/IV–TCNQ complex is assembled through Lewis acid-promoted donor–acceptor potential shifts providing a magnetic and luminescent compound.

Funder

Basic Energy Sciences

Vagelos Institute for Energy Science and Technology, University of Pennsylvania

University of Pennsylvania

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01478B

Reference48 articles.

1. Mixed Valency as a Strategy for Achieving Charge Delocalization in Semiconducting and Conducting Framework Materials

2. Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework

3. Intrinsic glassy-metallic transport in an amorphous coordination polymer

4. Electrically Conductive Metal–Organic Frameworks

5. Metal–Organic Framework Magnets

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