Copper-catalyzed chemoselective C–H functionalization of quinoxalin-2(1H)-ones with hexafluoroisopropanol-Reference-Cited by-同舟云学术

Copper-catalyzed chemoselective C–H functionalization of quinoxalin-2(1H)-ones with hexafluoroisopropanol

Published:2020 Issue:84 Volume:56 Page:12805-12808
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Su Hai-Yan¹²³⁴⁵,Zhu Xiao-Lei¹²³⁴⁵,Huang Yangen¹²³⁴⁵^ORCID,Xu Xiu-Hua⁶⁷⁸⁹¹⁰^ORCID,Qing Feng-Ling¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Biotechnology

3. Donghua University

4. Shanghai 201620

5. China

6. Key Laboratory of Organofluorine Chemistry

7. Center for Excellence in Molecular Synthesis

8. Shanghai Institute of Organic Chemistry

9. University of Chinese Academy of Science

10. Chinese Academy of Science

Abstract

New applications of 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) were reported in the copper-catalyzed chemoselective C–H hydroxyhexafluoroisobutylation and hexafluoroisopropoxylation of quinoxalin-2(1H)-ones.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC05623E

Reference61 articles.

1. A remarkable solvent effect of fluorinated alcohols on transition metal catalysed C–H functionalizations

2. Hexafluoroisopropanol as a highly versatile solvent

3. Fluorinated Alcohols: Magic Reaction Medium and Promoters for Organic Synthesis

4. Mild Synthesis of Sterically Congested Alkyl Aryl Ethers

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