NHC-catalyzed silylative dehydration of primary amides to nitriles at room temperature

Author:

Hota Pradip Kumar1234ORCID,Maji Subir1234ORCID,Ahmed Jasimuddin1234ORCID,Rajendran N. M.1234ORCID,Mandal Swadhin K.1234ORCID

Affiliation:

1. Department of Chemical Sciences

2. Indian Institute of Science Education and Research Kolkata

3. Mohanpur 741246

4. India

Abstract

An abnormal NHC acts as an efficient catalyst for catalytic silylative dehydration of primary amides to nitriles under ambient conditions.

Funder

Science and Engineering Research Board

Indian Institute of Science Education and Research Kolkata

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference40 articles.

1. L. R. Subramanian , Nitriles , in Science of Synthesis , ed. B. M. Trost and M. Lautens , Thieme , Stuttgart , 2011 , vol. 19, p. 79

2. V. R. C. Larock , Comprehensive Orgaanic Transformations , VCH Publishers , New York , 1989 , vol. XXXIV, p. 1160 S

3. Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts

4. Q. A. Acton , Nitriles-Advances in Research and Application , Scholarly Editions , Atlanta , 2013

5. A. J. Fatiadi , Preparation and synthetic applications of cyano compounds , in Triple-Bonded Functional Groups , ed. S. Patai and Z. Rappoport , John Wiley & Sons , Chichester, U.K. , 1983 , vol. 2

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