Heptaphosphide cluster anions bearing group 14 element amide functionalities-Reference-Cited by-同舟云学术

Heptaphosphide cluster anions bearing group 14 element amide functionalities

Published:2016 Issue:5 Volume:45 Page:1930-1936
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Quintero Gabriela Espinoza¹²³⁴⁵,Paterson-Taylor Isabelle¹²³⁴⁵,Rees Nicholas H.¹²³⁴⁵,Goicoechea Jose M.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. University of Oxford

3. Chemistry Research Laboratory

4. Oxford

5. UK

Abstract

Reactions of the protonated heptaphosphide dianion, [HP₇]²⁻, with one equivalent of E[N(SiMe₃)₂]₂(E = Ge, Sn, Pb) give rise to novel derivatized cluster anions [P₇EN(SiMe₃)₂]²⁻(E = Ge (1), Sn (2) and Pb (3)).1readily decomposes in solution at room temperature to afford the dimeric product [(P₇Ge)₂N(SiMe₃)₂]³⁻(4).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02380G

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