How does tuning the van der Waals bonding strength affect adsorbate structure?-Reference-Cited by-同舟云学术

How does tuning the van der Waals bonding strength affect adsorbate structure?

Published:2022 Issue:48 Volume:24 Page:29371-29380
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Maier Philipp¹^ORCID,Xavier Neubi F.²^ORCID,Truscott Chris L.³,Hansen Thomas⁴,Fouquet Peter⁴^ORCID,Sacchi Marco²^ORCID,Tamtögl Anton¹^ORCID

Affiliation:

1. Institute of Experimental Physics, Graz University of Technology, 8010 Graz, Austria

2. Department of Chemistry, University of Surrey, Guildford GU2 7XH, UK

3. Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK

4. Institut Laue-Langevin, 71 Avenue des Martyrs, 38000 Grenoble, France

Abstract

The binding and structure of an ordered pyrazine overlayer on graphite are studied with neutron scattering and DFT. We find increased van der Waals bonding and stability of the overlayer compared to benzene, due to the nitrogen atoms in the ring.

Funder

Royal Society

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP03468A

Reference65 articles.

1. Evolution of ordered nanoporous phases during h-BN growth: controlling the route from gas-phase precursor to 2D material by in situ monitoring

2. Toward Accurate and Efficient Predictions of Entropy and Gibbs Free Energy of Adsorption of High Nitrogen Compounds on Carbonaceous Materials

3. Noncovalent Interaction of Graphene with Heterocyclic Compounds: Benzene, Imidazole, Tetracene, and Imidazophenazines

4. Tailoring Electronic Properties of Graphene by π–π Stacking with Aromatic Molecules

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