Infrared multiple-photon dissociation spectroscopy of cationized glycine: effects of alkali metal cation size on gas-phase conformation

Author:

Armentrout P. B.1ORCID,Stevenson Brandon C.1,Ghiassee Maryam1,Boles Georgia C.1,Berden Giel2ORCID,Oomens Jos23ORCID

Affiliation:

1. Department of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, USA

2. Radboud University, FELIX Laboratory, Institute for Molecules and Materials, Toernooiveld 7, NL-6525 ED Nijmegen, The Netherlands

3. van’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, NL-1098 XH Amsterdam, The Netherlands

Abstract

The gas-phase structures of glycine (Gly) cationized with Li+, Na+, K+, Rb+, and Cs+ are examined using infrared multiple-photon dissociation (IRMPD) spectroscopy utilizing light generated by a free electron laser and with ab initio calculations.

Funder

Aard- en Levenswetenschappen, Nederlandse Organisatie voor Wetenschappelijk Onderzoek

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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