Synthetic, structural and reactivity studies of a boryl-ethynyl Silylene-Reference-Cited by-同舟云学术

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Synthetic, structural and reactivity studies of a boryl-ethynyl Silylene

Published:2024 Issue:45 Volume:60 Page:5828-5831
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Wenhao¹,Hu Haisheng¹,Feng Jie¹,Zhu Lei²^ORCID,Wu Di¹^ORCID

Affiliation:

1. College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China

2. School of Chemistry and Materials Science, Hubei Key Laboratory of Quality Control of Characteristic Fruits And Vegetables, Hubei Engineering University, Xiaogan, 432000, China

Abstract

The salt metathesis of a boryl-ethynyl lithium salt {[(HCDipN)2]B-CC-Li} with a monochlorosilylene [LSi(:)Cl; L = PhC(NtBu)2] gave rise to an isolable ethynyl silylene {[(HCDipN)2]B-CC-Si(L)}, confirmed by X-ray diffraction analysis and DFT calculations.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00922C

Reference62 articles.

1. Stable Silylenes

2. Stable Heavier Carbene Analogues

3. N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands

4. An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

5. Compounds with Low-Valent p-Block Elements for Small Molecule Activation and Catalysis

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