Intermetallic Ni2Si/SiCN as a highly efficient catalyst for the one-pot tandem synthesis of imines and secondary amines-Reference-Cited by-同舟云学术

Intermetallic Ni2Si/SiCN as a highly efficient catalyst for the one-pot tandem synthesis of imines and secondary amines

Published:2020 Issue:1 Volume:7 Page:82-90
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Chen Xiao¹²³⁴^ORCID,Han Shuhua¹²³⁴,Yin Dongdong¹²³⁴,Liang Changhai¹²³⁴^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals & Laboratory of Advanced Materials and Catalytic Engineering

2. Dalian University of Technology

3. Dalian 116024

4. China

Abstract

For the one-pot reductive amination of benzaldehyde with nitrobenzene, intermetallic Ni₂Si/SiCN from the decomposition of a nickel-modified polysilazane precursor exhibited high activity (>99%) and high selectivity (92% to aromatic amine).

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/C9QI01077G

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