Transition-metal-free oxidative carboazidation of acrylamides via cascade C–N and C–C bond-forming reactions
Author:
Affiliation:
1. Department of Chemistry
2. Tongji University
3. Shanghai 200092, P. R. China
4. Key Laboratory of Yangtze River Water Environment
5. Ministry of Education
Abstract
A novel transition-metal-free oxidative carboazidation of acrylamides using inexpensive NaN3 and K2S2O8 was achieved, which not only provided an efficient method to prepare various N3-substituted oxindoles, but also represented a novel strategy for C–N and C–C bond formation via a free-radical cascade process.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00720D
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