An artificially tailored functional layer on Li-rich layer cathodes enables a stable high-temperature interphase for Li-ion batteries

Author:

Yang Yaru1,Sun Gang12,Zhu Qingjun1,Jiang Yunshan3,Ke Wang3,Wang Panpan1,Zhao Yang4,Zhang Wang1,Wang Zhenbo123ORCID

Affiliation:

1. College of Materials Science and Engineering, Shenzhen University, Shenzhen 518071, China

2. College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China

3. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, State Key Lab of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, No. 92 West-Da Zhi Street, Harbin 150001, China

4. Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario, N6A 5B9, Canada

Abstract

The unstable electrode–electrolyte interphase of Li-rich cathodes limit their application. Here an ultrathin Li2SiO3 protective layer with super toughness and functionality is constructed on the surface of Li-rich cathodes by atom layer deposition.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

State Key Laboratory of Urban Water Resource and Environment

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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