Simple 1,3-diamines and their application as ligands in ruthenium(ii) catalysts for asymmetric transfer hydrogenation of aryl ketones
Author:
Affiliation:
1. Dipartimento di Scienze Farmaceutiche
2. Sez. Chimica Generale e Organica “A. Marchesini”
3. Università degli Studi di Milano
4. 20133 Milano
5. Italy
Abstract
A new efficient synthesis of 1,3-diamines was realized and their ruthenium(ii) complexes were studied in ATH in aqueous media.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00110B
Reference46 articles.
1. Asymmetric homogeneous hydrogenations at scale
2. Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes
3. The Catalyst Precursor, Catalyst, and Intermediate in the RuII-Promoted Asymmetric Hydrogen Transfer between Alcohols and Ketones
4. Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation Using Unsymmetrical Vicinal Diamine-Based Ligands: Dramatic Substituent Effect on Catalyst Efficiency
5. Synthesis of a water-soluble cationic chiral diamine ligand bearing a diguanidinium and application in asymmetric transfer hydrogenation
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