High-efficiency electrochemical nitrite reduction to ammonium using a Cu3P nanowire array under ambient conditions

Author:

Liang Jie1234,Deng Biao1234ORCID,Liu Qin1234,Wen Guilai1234,Liu Qian5674ORCID,Li Tingshuai1234,Luo Yonglan5674ORCID,Alshehri Abdulmohsen Ali89101112,Alzahrani Khalid Ahmed89101112,Ma Dongwei131415164ORCID,Sun Xuping1234ORCID

Affiliation:

1. Institute of Fundamental and Frontier Sciences

2. University of Electronic Science and Technology of China

3. Chengdu 610054

4. China

5. Institute for Advanced Study

6. Chengdu University

7. Chengdu 610106

8. Chemistry Department

9. Faculty of Science

10. King Abdulaziz University

11. Jeddah 21589

12. Saudi Arabia

13. Key Laboratory for Special Functional Materials of Ministry of Education

14. School of Materials Science and Engineering

15. Henan University

16. Kaifeng 475004

Abstract

Cu3P enables ambient electrosynthesis of ammonium via selective NO2 reduction, achieving a yield rate of 1626.6 ± 36.1 μg h−1 cm−2 and a Faradaic efficiency of 91.2 ± 2.5%. The catalytic mechanism is investigated by theoretical calculations.

Funder

Department of Science and Technology of Sichuan Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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