Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene–zinc iodide adducts-Reference-Cited by-同舟云学术

Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene–zinc iodide adducts

Published:2017 Issue:34 Volume:46 Page:11418-11424
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yadav Sandeep¹²³⁴⁵,Sangtani Ekta⁵⁶⁴⁷²,Dhawan Diksha⁷²³⁴,Gonnade Rajesh G.⁵⁶⁴⁷²^ORCID,Ghosh Debashree⁸⁹¹⁰⁴^ORCID,Sen Sakya S.¹²³⁴⁵^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis Division

2. CSIR-National Chemical Laboratory

3. Pune 411008

4. India

5. Academy of Scientific and Innovative Research (AcSIR)

6. New Delhi-110020

7. Physical and Material Chemistry Division

8. Department of Physical Chemistry

9. Indian Association for the Cultivation of Science

10. Kolkata 700032

Abstract

The reaction of silylene [PhC(NtBu)₂SiN(SiMe₃)₂] with ZnI₂leads to both monomeric [PhC(NtBu)₂Si{N(SiMe₃)₂} → ZnI₂]·THF (1) and dimeric [PhC(NtBu)₂Si{N(SiMe₃)₂} → ZnI₂]₂(2) adducts which are inter-convertible.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01823A

Reference73 articles.

1. Synthesis and Characterization of [PhC(NtBu)2]SiCl: A Stable Monomeric Chlorosilylene

2. High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

3. Striking Stability of a Substituted Silicon(II) Bis(trimethylsilyl)amide and the Facile Si–Me Bond Cleavage without a Transition Metal Catalyst

4. Stable silylenes: synthesis, structure, reactions

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