First isolation of fully delocalized mixed-valent imido-bridged [Ti2]7+ complexes by one-electron reduction of [(C5R5)TiCl]2(μ-NAr)2-Reference-Cited by-同舟云学术

First isolation of fully delocalized mixed-valent imido-bridged [Ti2]7+ complexes by one-electron reduction of [(C5R5)TiCl]2(μ-NAr)2

Published:2011 Issue:19 Volume:47 Page:5620-5622
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tsurugi Hayato¹²³⁴⁵,Nagae Haruki¹²³⁴⁵,Mashima Kazushi¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Engineering Science

3. Osaka University, and CREST

4. JST

5. Osaka 560-8531

Abstract

Fully delocalized mixed-valent [Ti₂]⁷⁺ species were isolated by the reduction of imido-bridged binuclear Ti₂ complexes with Cp₂Co.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2011/CC/C1CC10757G

Reference40 articles.

1. New amido- and imido-titanium complexes

2. Dimers of highly π-loaded organoimido d1 metal radicals of niobium, tantalum, molybdenum, tungsten, and rhenium: the context of the cyclopentadienyl imido ligand analogy

3. t-Butylimido compounds of rhenium. X-ray crystal structures of [(ButN)2Re(μ-NBut)]2, (ButN)2ReCl3, (ButN)2ReCl2C6H5, (ButN)3Re(OSiMe3) and (ButN)3ReCl

4. Interconversion of oxo and imido ligands at a dimolybdenum centre: molecular and electronic structure of [{Mo(η-C5H4Me)(NPh)(µ-NPh)}2]

5. The interconversion of oxo and imido ligands at a dimolybdenum centre: X-ray crystal structure of [Mo(η-C5H4Me)(NPh)(μ-NPh)]2

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