Peculiar bond characters of fivefold coordinated octet compound crystals
Author:
Affiliation:
1. Department of Materials Science
2. Fudan University
3. Shanghai 200433
4. China
5. Min H. Kao Department of Electrical Engineering and Computer Science
6. University of Tennessee
7. Knoxville
8. USA
Abstract
A refreshed view of chemical bonds in solids unveils unusual bonding in fivefold coordinated bulk crystals of octet compounds: out-of-plane cation–anion chain bonding via overlapping pz orbitals replaces in-plane π bonding of the isolated monolayer.
Funder
Division of Materials Research
Natural Science Foundation of Shanghai
Army Research Office
Shanghai Municipal Education Commission
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00292E
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