Real-time observation of sub-100-fs charge and energy transfer processes in DNA dinucleotides

Author:

Petropoulos Vasilis1ORCID,Martinez-Fernandez Lara2,Uboldi Lorenzo1ORCID,Maiuri Margherita1ORCID,Cerullo Giulio13ORCID,Balanikas Evangelos4ORCID,Markovitsi Dimitra5ORCID

Affiliation:

1. Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy

2. Instituto de Química Física Blas Cabrera, Consejo Superior de Investigaciones Científicas, Calle Serrano 119, Madrid, 28006, Spain

3. Istituto di Fotonica e Nanotecnologie-CNR, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy

4. Department of Physical Chemistry, University of Geneva, CH-1211 Geneva-4, Switzerland

5. Université Paris-Saclay, CNRS, Institut de Chimie Physique, UMR8000, 91405 Orsay, France

Abstract

Using as showcase the DNA dinucleotide 5′-dTpdG-3′, in which the thymine is located at the 5′ end with respect to the guanine, we study the photoinduced electronic relaxation of coupled chromophores in solution with an unprecedented refinement.

Funder

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

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