Melting pseudosymmetry and thermal expansion in 3-benzoylpropionic acid

Author:

Poręba Tomasz12ORCID,Świątkowski Marcin3ORCID,Confalonieri Giorgia1ORCID

Affiliation:

1. European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France

2. Laboratory of Quantum Magnetism, Institute of Physics, École Polytechnique Federale de Lausanne, Lausanne CH-1015, Switzerland

3. Institute of General and Ecological Chemistry, Lodz University of Technology, Żeromskiego 116, 90-924 Łódź, Poland

Abstract

3-Benzoylpropionic acid undergoes continuous transition associated with pseudosymmetry melting upon heating. The transition stems from a directional steric crowding, which refutes the recent premise of its colossal thermal expansion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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