A(VO2F)(SeO3) (A = Sr, Ba) and Ba(MOF2)(TeO4) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d0-TM octahedron
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou 350002
5. China
Abstract
First examples of alkali-earth selenites/tellurites with a fluorinated d0-TM octahedron, namely, A(VO2F)(SeO3) (A = Sr 1, Ba 2) and Ba(MOF2)(TeO4) (M = Mo 3, W 4), were synthesized successfully by hydrothermal reactions.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04442A
Reference46 articles.
1. Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals
2. Structures and Properties of Functional Metal Selenites and Tellurites
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4. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures
5. Syntheses, Crystal Structures, and Properties of New Layered Molybdenum(VI) Selenites: (NH4)2(MoO3)3SeO3 and Cs2(MoO3)3SeO3
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