Highly enantioselective asymmetric Henry reaction catalyzed by novel chiral phase transfer catalysts derived from cinchona alkaloids-Reference-Cited by-同舟云学术

Highly enantioselective asymmetric Henry reaction catalyzed by novel chiral phase transfer catalysts derived from cinchona alkaloids

Published:2016 Issue:42 Volume:14 Page:10101-10109
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Vijaya Ponmuthu Kottala¹²³⁴⁵,Murugesan Sepperumal¹²³⁴⁵,Siva Ayyanar¹²³⁴⁵

Affiliation:

1. Department of Inorganic Chemistry

2. School of Chemistry

3. Madurai Kamaraj University

4. Madurai-625 021

5. India

Abstract

Newly synthesized CPTCs are applied in the asymmetric Henry reaction to a wide range of aldehydes under mild reaction conditions, and we obtained higher chemical yields and an excellent enantiomeric excess.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB01687A

Reference61 articles.

1. The Henry reaction: recent examples

2. Synthesis of (S)-(+)-sotalol and (R)-(−)-isoproterenol via a catalytic enantioselective Henry reaction

3. Enantioselective synthesis of (R)-salmeterol employing an asymmetric Henry reaction as the key step

4. Effect of Ligand Structure on the Zinc-Catalyzed Henry Reaction. Asymmetric Syntheses of (−)-Denopamine and (−)-Arbutamine

5. A total synthesis of (−)-bestatin using Shibasaki’s asymmetric Henry reaction

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