Ambient N2 fixation to NH3 electrocatalyzed by a spinel Fe3O4 nanorod

Author:

Liu Qin12345,Zhang Xiaoxue12345,Zhang Bing6785,Luo Yonglan910115,Cui Guanwei121314155,Xie Fengyu1617185,Sun Xuping12345ORCID

Affiliation:

1. Key Laboratory of Chemical Synthesis and Pollution Control of Sichuan Province

2. School of Chemistry and Chemical Engineering

3. China West Normal University

4. Nanchong 637002

5. China

6. Leshan Environmental Monitoring Center Station

7. Leshan Environmental Protection

8. Leshan 614000

9. Institute of Fundamental and Frontier Science

10. University of Electronic Science and Technology of China

11. Chengdu 610054

12. College of Chemistry

13. Chemical Engineering and Materials Science

14. Shandong Normal University

15. Jinan 250014

16. College of Chemistry and Materials Science

17. Sichuan Normal University

18. Chengdu 610068

Abstract

A spinel Fe3O4 nanorod on a Ti mesh is a superior catalyst for electrochemical N2 fixation to NH3 in 0.1 M Na2SO4, achieving a high FE of 2.6% with a NH3 yield of 5.6 × 10−11 mol s−1 cm−2 at a potential of −0.4 V vs. a reversible hydrogen electrode.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Reference26 articles.

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2. V. Smil , Enriching the earth: Fritz Haber, Carl Bosch, and the transformation of world food production , MIT Press , Cambridge, MA , 2004

3. Mineral Commodity Summaries 2016 , U.S. Geological Survey , U.S. Government Printing Office , Washington, DC , 2016

4. Au Sub-Nanoclusters on TiO2toward Highly Efficient and Selective Electrocatalyst for N2Conversion to NH3at Ambient Conditions

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