Impact of crystal structure on the lattice thermal conductivity of the IV–VI chalcogenides

Author:

Guillemot Sophie K.12ORCID,Suwardi Ady2ORCID,Kaltsoyannis Nikolas1ORCID,Skelton Jonathan M.1ORCID

Affiliation:

1. Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK

2. Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 1 Fusionopolis Way, #20-10 Connexis North Tower, Singapore 138632, Singapore

Abstract

A detailed analysis of the lattice thermal conductivity of ten Group IV–VI chalcogenides demonstrates that the κlatt is a balance of the phonon group velocities, the anharmonic interaction strengths, and the scattering “phase space”, all of which can be linked to the crystal structure.

Funder

Engineering and Physical Sciences Research Council

Agency for Science, Technology and Research

UK Research and Innovation

University of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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