The synthesis and application of novel Ni(ii) N-alkyl dipyridylaldiminato complexes as selective ethylene oligomerisation catalysts-Reference-Cited by-同舟云学术

The synthesis and application of novel Ni(ii) N-alkyl dipyridylaldiminato complexes as selective ethylene oligomerisation catalysts

Published:2014 Issue:26 Volume:43 Page:9892-9900
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Swarts Andrew J.¹²³,Mapolie Selwyn F.¹²³

Affiliation:

1. Stellenbosch University

2. Department of Chemistry and Polymer Science

3. Matieland, South Africa

Abstract

A series of dinuclear Cl-bridged Ni(ii) complexes, 1a–1e, ligated by N-alkyl 2,2′-dipyridylamine ligands displayed high activity in ethylene oligomerisation, when activated with alkyl aluminium reagents. Steric and electronic effects as well as activation pathways were found to have a significant impact on catalyst activity and selectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00537F

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